The RMIT University team led by Dr Dorna Esrafilzadeh and Dr Rouhollah Ali Jalili inspected commercially-available graphene samples, atom by atom, with a state-of-art scanning transition electron microscope.
“We found high levels of silicon contamination in commercially available graphene, with massive impacts on the material’s performance,” Esrafilzadeh said.
Testing showed that silicon present in natural graphite, the raw material used to make graphene, was not being fully removed when processed.
“We believe this contamination is at the heart of many seemingly inconsistent reports on the properties of graphene and perhaps many other atomically thin two-dimensional (2D) materials,” Esrafilzadeh said.
“Graphene was billed as being transformative, but has so far failed to make a significant commercial impact, as have some similar 2D nanomaterials. Now we know why it has not been performing as promised, and what needs to be done to harness its full potential.”
The testing not only identified these impurities but also demonstrated the major influence they have on performance, with contaminated material performing up to 50% worse when tested as electrodes.
“This level of inconsistency may have stymied the emergence of major industry applications for graphene-based systems. But it’s also preventing the development of regulatory frameworks governing the implementation of such layered nanomaterials, which are destined to become the backbone of next-generation devices,” she said.
The two-dimensionalproperty of graphene sheeting, which is only one atom thick, makes it ideal for electricity storage and new sensor technologies that rely on high surface area.
This study reveals how that 2D property is also graphene’s Achilles’ heel, by making it so vulnerable to surface contamination, and underscores how important high purity graphite is for the production of more pure graphene.
Using pure graphene, researchers demonstrated how the material performed extraordinarily well when used to build a supercapacitator, a kind of super battery.
When tested, the device’s capacity to hold electrical charge was massive. In fact, it was the biggest capacity so far recorded for graphene and within sight of the material’s predicted theoretical capacity.
In collaboration with RMIT’s Centre for Advanced Materials and Industrial Chemistry, the team then used pure graphene to build a versatile humidity sensor with the highest sensitivity and the lowest limit of detection ever reported.
These findings constitute a vital milestone for the complete understanding of atomically thin two-dimensional materials and their successful integration within high performance commercial devices.
“We hope this research will help to unlock the exciting potential of these materials.”
The article “Silicon as a ubiquitous contaminant in graphene derivatives with significant impact on device performance” is published in Nature Communication: DOI: 10.1038/s41467-018-07396-3